Wang, Dean-Jay, and Shan-hui Hsu. Materials Today Communications 39 (2024): 109351.
Polyoxyethylene tridecyl ether plays a critical role in the stabilization of novel waterborne polyurethane (WBPU) systems, particularly those designed for biomedical applications. In a recent synthesis strategy, polyoxyethylene tridecyl ether was employed in conjunction with polyoxyethylene styrenated phenyl to form a nonionic surfactant system that effectively emulsifies high-solid-content polyurethane prepolymers.
The WBPU formulation is based on soft segments comprising polycarbonate diol (PCDL) and polytetramethylene ether glycol, with 4,4'-methylene dicyclohexyl diisocyanate as the diisocyanate component. Dimethylolbutanoic acid serves as the internal emulsifier, introducing carboxylic acid groups later neutralized by triethylamine. Upon emulsification with the nonionic surfactant system-where polyoxyethylene tridecyl ether constitutes 50%-the neutralized prepolymer forms a stable dispersion upon addition of deionized water and subsequent chain extension with ethylenediamine.
The surfactant system ensures uniform particle distribution, reduces viscosity, and enhances the long-term colloidal stability of the WBPU dispersion. The resulting polymer exhibited 45% solid content and demonstrated excellent hydrophilicity and hemocompatibility-attributes essential for biomedical use.
Thus, polyoxyethylene tridecyl ether is indispensable in synthesizing advanced WBPUs, offering not only emulsification efficiency but also compatibility with biomedical-grade materials. Its use exemplifies the integration of tailored surfactants into next-generation polymeric dispersions.
What is the CAS number of Ethoxylated tridecyl alcohol?
The CAS number of Ethoxylated tridecyl alcohol is 24938-91-8.
What are some synonyms of Ethoxylated tridecyl alcohol?
Some synonyms of Ethoxylated tridecyl alcohol include PEG Tridecyl ether, Polyethylene glycol tridecyl ether, and Polyoxyethylene tridecyl ether.
What is the IUPAC name of Ethoxylated tridecyl alcohol?
The IUPAC name of Ethoxylated tridecyl alcohol is 2-tridecoxyethanol.
What is the molecular formula of Ethoxylated tridecyl alcohol?
The molecular formula of Ethoxylated tridecyl alcohol is (C2H4O)n.C13H28O.
What is the boiling point of Ethoxylated tridecyl alcohol?
The boiling point of Ethoxylated tridecyl alcohol is >150°C.
What is the melting point of Ethoxylated tridecyl alcohol?
The melting point of Ethoxylated tridecyl alcohol is 28°C.
What is the physical state of Ethoxylated tridecyl alcohol?
The physical state of Ethoxylated tridecyl alcohol is solid.
What is a typical application of Ethoxylated tridecyl alcohol?
A typical application of Ethoxylated tridecyl alcohol is as an emulsifying agent.
What percentage of actives does Ethoxylated tridecyl alcohol contain?
Ethoxylated tridecyl alcohol contains 95% actives.