Pang, Kun, et al. Journal of Environmental Chemical Engineering (2025): 117705.
Polyethylene terephthalate (PET), a common plastic waste, was successfully upcycled into high-value phosphorus and nitrogen co-doped porous carbon nanobulks (PN/PCNs) via a facile one-pot pyrolysis method. In this process, 1 g of PET and 1 g of ammonium polyphosphate (APP) were thoroughly ground for 3 minutes to obtain a homogeneous precursor mixture. The powder was then calcined in a tube furnace at 500, 550, or 600 °C for 1 hour under a heating rate of 5 °C·min⁻¹. The resulting carbonaceous products were washed three times with deionized water to remove soluble impurities and dried at 60 °C overnight. Final yields were approximately 150 mg per synthesis, denoted as PN/PCN-x based on calcination temperature.
The catalytic degradation performance was evaluated using sulfadiazine (SDZ) as a model pollutant. A 50 mL aqueous SDZ solution (20 mg·L⁻¹) was treated with 15 mg of peroxymonosulfate (PMS) and 6 mg of PN/PCN catalyst under continuous stirring at 30 °C. UV-vis spectrophotometry was used to monitor degradation at timed intervals. Among the samples, PN/PCN-550 exhibited superior activity with a 91.95% degradation efficiency and 71.1% mineralization rate. Mechanistic analysis revealed O₂·⁻, ¹O₂, and ·OH as primary reactive species.
This study highlights the effective use of PET in synthesizing advanced carbon-based catalysts for environmental remediation.
Tiwari, Rishabh, Mohamed A. Abdelwahab, and Muhammad Rabnawaz. Polymer (2025): 128761.
This study explores the preparation of advanced polyethylene terephthalate (PET)-based blends by melt blending PET with liquid crystal polymer (LCP) and polyglycolic acid (PGA), aimed at enhancing barrier, thermal, and mechanical properties. Blends were prepared using a DSM Xplore twin-screw micro-compounder under nitrogen atmosphere at 250 °C, with a screw speed of 100 rpm and a mixing time of 120 s. Prior to blending, PET, LCP/PGA, and Joncryl ADR (compatibilizer) were dried at 80 °C for 24 hours.
Each blend was extruded into continuous strands, cut into pellets, and subsequently processed into films via compression molding at 270 °C under 10 tonnes of pressure. Films were rapidly quenched using dry ice in a thermally insulated setup to prevent crystallization defects.
Scanning electron microscopy confirmed improved interfacial adhesion in PET/LCP and PET/PGA blends with Joncryl addition. Notably, the PET/20% PGA blend exhibited significant improvements in oxygen (62%) and water vapor (41%) barrier properties compared to neat PET. Mechanical testing showed a 42% increase in tensile strength and 22.4% in modulus, highlighting PGA's reinforcement potential.
This study demonstrates that PET, when compatibilized and blended with LCP or PGA, forms recyclable polyester-based materials with enhanced performance, suitable for high-barrier packaging or engineering applications.
Liu, Mengyun, et al. RSC advances 15.14 (2025): 11023-11033.
Polyethylene terephthalate (PET) is used as the outer structural layer in a bilayer film system developed for the active packaging and preservation of Lycium barbarum (goji berries). In this study, PET provides mechanical strength and barrier protection, complementing an inner chitosan/polyvinyl alcohol (CS/PVA) film infused with white round grapefruit essential oil (WRGEO). The bilayer was fabricated via solution casting, integrating antimicrobial and moisture-retention functionalities for food preservation applications.
The PET layer served as a robust support for the bioactive CS/PVA inner film, which contained 1% v/v WRGEO as the key functional additive. Gas chromatography-mass spectrometry identified d-limonene and other monoterpenes in WRGEO with potent antimicrobial activity against E. coli, S. aureus, and A. niger. While the essential oil enhanced flexibility and thermal stability of the CS/PVA layer, PET maintained the composite film's dimensional integrity and provided effective moisture and oxygen barrier properties.
When applied to packaging Lycium barbarum, the PET-based bilayer film significantly reduced water loss, decay rate, and malondialdehyde accumulation while preserving color and extending shelf life compared to unpackaged controls. The integration of PET into this dual-functional film system highlights its utility in developing next-generation bioactive packaging solutions, merging mechanical durability with natural antimicrobial strategies for postharvest preservation.